Enantiodivergent Formal Synthesis of (+)- and (−)-Cyclophellitol from d-Xylose Based on the Latent Symmetry Concept
The Journal of Organic Chemistry2004Vol. 70(2), pp. 742–745
Citations Over TimeTop 18% of 2004 papers
Abstract
Formal synthesis of (+)- and (-)-cyclophellitol from d-xylose has been accomplished through utilization of the latent plane of chirality present in the starting carbohydrate. The synthetic pathway is suitable for preparation and biological evaluation of cyclophellitol analogues in both enantiomeric series.
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