Reactivity of Phthalimide N-Oxyl Radical (PINO) toward the Phenolic O−H Bond. A Kinetic Study
The Journal of Organic Chemistry2004Vol. 69(25), pp. 8963–8966
Citations Over TimeTop 18% of 2004 papers
Abstract
The reactivity of the phthalimide N-oxyl radical (PINO) toward the OH bond of a series of substituted phenols was kinetically investigated in CH(3)CN. The reaction selectivity and the deuterium kinetic isotope effect were determined. Information on the kinetic solvent effect was also obtained with phenol as the substrate.
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