Alkynyliodonium Salts in Organic Synthesis. Application to the Preparation of the Tricyclic Core of (±)-Halichlorine
The Journal of Organic Chemistry2004Vol. 69(23), pp. 7928–7932
Citations Over TimeTop 11% of 2004 papers
Abstract
The tricyclic core of halichlorine has been synthesized through the use of an alkynyliodonium salt/alkylidenecarbene/1,5 C-H insertion sequence that sets the pivotal quaternary center in the target.
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