A Fine-Tuned Molybdenum Hexacarbonyl/Phenol Initiator for Alkyne Metathesis
The Journal of Organic Chemistry2004Vol. 69(22), pp. 7748–7751
Citations Over TimeTop 10% of 2004 papers
Abstract
A new, highly potent activator for molybdenum hexacarbonyl and 2-fluorophenol is described. An "instant"catalyst formed in situ from molybdenum hexacarbonyl and 2-fluorophenol shows high activity for cross- and ring-closing alkyne metathesis reaction. The use of 2-fluorophenol can be combined with other activation methods to allow alkyne metathesis at relatively low temperature (80 degrees C).
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