Palladium Complexes of 1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane: Synthesis, Crystal Structure and Use in the Suzuki and Sonogashira Reactions and the α-Arylation of Ketones
The Journal of Organic Chemistry2004Vol. 69(15), pp. 5082–5086
Citations Over TimeTop 10% of 2004 papers
George M. Adjabeng, T. Brenstrum, Christopher S. Frampton, Al Robertson, John H. Hillhouse, James McNulty, Alfredo Capretta
Abstract
Palladium complexes of 1,3,5,7-tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane were prepared and characterized with Pd[1,3,5,7-tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane](2).dba shown to be an effective catalyst for use in the Suzuki and Sonogashira reactions and the alpha-arylation of ketones. Couplings using this versatile complex proceeded in excellent yields under mild conditions.
Related Papers
- → A novel one-pot three-component synthesis of 3-halofurans and sequential Suzuki coupling(2005)80 cited
- → Sequential Sonogashira and Suzuki Cross-Coupling Reactions in the Indole and Indazole Series(2005)45 cited
- → Multiple Sonogashira Reactions of Polychlorinated Molecules. Synthesis and Photophysical Properties of the First Pentaalkynylpyridines(2011)39 cited
- → Preparation of organo palladium sols from palladium complexes in various alcohols(1994)32 cited
- → The constitution of cerium-palladium alloys containing 50–100% palladium(1967)48 cited