Efficient Reductive Selenation of Aromatic Aldehydes to Symmetrical Diselenides with Se/CO/H2O under Atmospheric Pressure
The Journal of Organic Chemistry2004Vol. 69(13), pp. 4520–4523
Citations Over TimeTop 22% of 2004 papers
Abstract
An efficient method for the synthesis of symmetrical diselenides is described. Reductive selenation of aromatic and heterocyclic aromatic aldehydes (ArCHO) with Se/CO/H(2)O in DMF afforded diselenides (ArCH(2)SeSeCH(2)Ar) in yields up to 94% under atmospheric pressure without use of a base.
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