Stereoselective Synthesis of the C1−C13 Fragment of 2,3-Dihydrodorrigocin A
The Journal of Organic Chemistry2005Vol. 70(20), pp. 8212–8215
Citations Over TimeTop 24% of 2005 papers
Abstract
[Chemical reaction: see text] The first synthesis of the C1-C13 fragment of 2,3-dihydrodorrigocin A has been achieved from 6-bromohexanoic acid in 14 linear steps and an overall yield of 2%. The configurations of the stereogenic centers C8, C9, and C10 have been determined to be the same as for migrastatin.
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