New Catalysts for Suzuki−Miyaura Coupling Reactions of Heteroatom-Substituted Heteroaryl Chlorides
The Journal of Organic Chemistry2007Vol. 72(14), pp. 5104–5112
Citations Over TimeTop 10% of 2007 papers
Anil S. Guram, Xiang Wang, Emilio E. Bunel, Margaret M. Faul, Robert D. Larsen, Michael J. Martinelli
Abstract
The new air-stable PdCl2[PR2(Ph-R')]2 complexes, readily prepared from commercial reagents, exhibit unique efficiency as catalysts for the Suzuki-Miyaura coupling reactions of a variety of heteroatom-substituted heteroaryl chlorides with a diverse range of aryl/heteroaryl boronic acids. The coupling reactions catalyzed by the new complexes exhibit high product yields (88-99%) and high catalyst turnover numbers (up to 10,000 TON).
Related Papers
- → trans-Pd(OAc)2(Cy2NH)2 catalyzed Suzuki coupling reactions and its temperature-dependent activities toward aryl bromides(2003)76 cited
- → Reusable polymer-supported palladium catalysts: An alternative to tetrakis(triphenylphosphine)palladium in the Suzuki cross-coupling reaction(1998)142 cited
- → Synthesis of novel fluorescent 3-aryl- and 3-methyl-7-aryl-[1,2,3]triazolo[1,5-a]pyridines by Suzuki cross-coupling reactions(2006)27 cited
- → Synthesis of N-aryl trifluoromethylarylketoimines by palladium-catalyzed Suzuki coupling reaction of N-aryltrifluoroacetimidoyl chlorides with aryl boronic acids(2010)12 cited
- → ChemInform Abstract: Synthesis of N‐Aryl Trifluoromethylarylketoimines by Palladium‐Catalyzed Suzuki Coupling Reaction of N‐Aryltrifluoroacetimidoyl Chlorides with Aryl Boronic Acids.(2010)