Fluorocyanation of Enamines
The Journal of Organic Chemistry2010Vol. 75(15), pp. 5367–5370
Citations Over TimeTop 12% of 2010 papers
Alexander D. Dilman, Pavel A. Belyakov, Марина И. Стручкова, Dmitry E. Arkhipov, Аlexander А. Korlyukov, Vladimir A. Tartakovsky
Abstract
A method for the fluorocyanation of enamines has been described. The reaction involves fluorination of the electron rich double bond with N-F reagent (Selectfluor or NFSI) accompanied by trapping of beta-fluoroiminium cationic intermediate with cyanide nucleophile.
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