Radical Reaction of [60]Fullerene with Phosphorus Compounds Mediated by Manganese(III) Acetate
The Journal of Organic Chemistry2011Vol. 76(15), pp. 6088–6094
Citations Over TimeTop 10% of 2011 papers
Abstract
Radical reaction of [60]fullerene with phosphonates or phosphine oxide mediated by manganese(III) acetate dihydrate in chlorobenzene under three different conditions afforded three different types of phosphorylated fullerenes: singly bonded fullerene dimers 2, hydrophosphorylated fullerenes 3, and acetoxylated fullerene derivatives 4. In addition, interconversions among the three types of phosphorylated fullerene derivatives have also been investigated. A possible reaction mechanism was proposed to explain experimental results.
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