Asymmetric Synthesis of Sulfinamides Using (−)-Quinine as Chiral Auxiliary
The Journal of Organic Chemistry2011Vol. 77(1), pp. 690–695
Citations Over Time
Yongda Zhang, Sampada Chitale, Navneet Goyal, Guisheng Li, Zhengxu S. Han, Sherry Shen, Shengli Ma, Nelu Grinberg, Heewon Lee, Bruce Z. Lu, Chris H. Senanayake
Abstract
A process has been designed and demonstrated for the asymmetric synthesis of sulfinamides using quinine as auxiliary. A variety of chiral sulfinamides including N-alkyl sulfinamides with diverse structure were prepared in good yields and excellent enantioselectivity starting from easily available and inexpensive reagents. The auxiliary quinine could be recovered and recycled.
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