Difluoro(trimethylsilyl)acetonitrile: Synthesis and Fluoroalkylation Reactions
The Journal of Organic Chemistry2012Vol. 77(13), pp. 5850–5855
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Abstract
A new silicon reagent, difluoro(trimethylsilyl)acetonitrile, was prepared by insertion of difluorocarbene into silyl cyanide. The obtained silane served as a good cyanodifluoromethylating reagent toward aldehydes, N-tosylimines, N-alkylimines, and enamines under basic or acidic conditions.
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