Copper-Catalyzed Allylation of α,α-Difluoro-Substituted Organozinc Reagents
The Journal of Organic Chemistry2013Vol. 79(2), pp. 818–822
Citations Over TimeTop 10% of 2013 papers
Abstract
A method for the coupling of organozinc reagents, difluorocarbene, and allylic electrophiles is described. The reaction involves insertion of difluorocarbene into the carbon-zinc bond followed by copper-catalyzed allylic substitution.
Related Papers
- → Pd-Catalyzed Transfer of Difluorocarbene(2016)132 cited
- → Allylic Phosphates and Allylic Phosphinates as Electrophiles in Efficient Silylcupration Reactions of Acetylenes(2002)37 cited
- → Reaction of quinoxalin-2-ones with difluorocarbene(1992)28 cited
- → Difluoromethylation of alcohols with TMSCF2Br in water: A new insight into the generation and reactions of difluorocarbene in a two-phase system(2020)15 cited
- → A photoprecursor for difluorocarbene(2002)6 cited