Oxidative Rearrangement of Tertiary Allylic Alcohols Employing Oxoammonium Salts
The Journal of Organic Chemistry2008Vol. 73(12), pp. 4750–4752
Citations Over TimeTop 10% of 2008 papers
Abstract
Practical and highly efficient methods for oxidative rearrangement of tertiary allylic alcohols to beta-substituted alpha,beta-unsaturated carbonyl compounds employing oxoammonium salts are described. The methods developed are applicable to acyclic substrates as well as medium membered ring substrates and macrocyclic substrates. The counteranion of the oxoammonium salt plays crucial roles on this oxidative rearrangement.
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