Benzothiazines in Synthesis. A Formal Total Synthesis of Pseudopteroxazole
The Journal of Organic Chemistry2009Vol. 74(15), pp. 5559–5561
Citations Over TimeTop 18% of 2009 papers
Abstract
A formal total synthesis of the antitubercular natural product was accomplished. This work was undertaken to address certain stereochemical problems in our initial synthesis. By using an ester group as a surrogate for a methyl group, we were able to intercept a key intermediate in our first synthesis with better selectivity and greater convergence than had previously been the case.
Related Papers
- → Total Synthesis, Structure Revision, and Absolute Configuration of (+)-Yatakemycin(2004)99 cited
- → Total synthesis of ent-(−)-azonazine using a biomimetic direct oxidative cyclization and structural reassignment of natural product(2014)24 cited
- → Diastereoselective Total Synthesis of (+)-13-Stemarene by Fourth Generation Methods: A Formal Total Synthesis of (+)-18-Deoxystemarin(2011)19 cited
- → Total Synthesis of a Marine Macrolide Natural Product, Iriomoteolide-2a: The Fundamental Role of Total Synthesis in Natural Product Chemistry(2019)2 cited
- → ChemInform Abstract: Merging Chemical Synthesis and Biosynthesis: A New Chapter in the Total Synthesis of Natural Products and Natural Product Libraries(2012)