Advantageous Use of tBu2P-N═P(iBuNCH2CH2)3N in the Hiyama Coupling of Aryl Bromides and Chlorides
The Journal of Organic Chemistry2010Vol. 75(5), pp. 1744–1747
Citations Over TimeTop 10% of 2010 papers
Abstract
An efficient catalytic route to biaryls by employing (generally) only 0.25 mol % of Pd(OAc)(2) and 0.5 mol % of 1 in the Hiyama coupling reaction is reported. High yields for electron-rich, -neutral, and -deficient aryl chlorides are obtained. A variety of phenylsiloxanes undergo coupling with aryl bromides and chlorides with low Pd(OAc)(2)/1 loadings.
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