(Trimethylstannyl)vinyl Cuprates: Generation and Conjugate Addition Reactions
The Journal of Organic Chemistry1996Vol. 61(16), pp. 5406–5413
Citations Over TimeTop 18% of 1996 papers
Abstract
A new convenient route to the bis[(trimethylstannyl)vinyl] cuprate reagent 9 is described. Its addition to α,β-unsaturated ketones has been studied. Bis(trimethylsilyl)acetamide (BSA) was found to activate 1,4-conjugate addition of 9 to α,β-unsaturated ketone esters without concomitant reduction of the double bond.
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