Asymmetric Synthesis of Activated α-Amino Esters via Chromium Carbene Complex Photochemistry
The Journal of Organic Chemistry1997Vol. 62(22), pp. 7704–7710
Citations Over TimeTop 22% of 1997 papers
Abstract
Optically active chromium aminocarbene complexes were α-alkylated and then photolyzed in the presence of 2,4,5-trichlorophenol to produce a number of optically active activated α-amino esters. These underwent coupling with amino acid esters or a soluble PEG-supported dipeptide to introduce the chromium−carbene-complex-derived amino acid residue into the peptide.
Related Papers
- → Genuine carbene versus carbene‐like reactivity(2024)17 cited
- → A Stable Four-Membered N-Heterocyclic Carbene(2004)139 cited
- → Stabilization of the Elusive 9‐Carbene‐9‐Borafluorene Monoanion(2021)12 cited
- → Preparation of new hydridoplatinum(II) carbene derivatives from hydridotrifluoromethyl complexes(1985)27 cited
- → Carbene Complexes — Complexes with MC Double Bonds(2021)