Preparation of 4-Substituted Benzyl Sulfoxylates and Related Chemistry
The Journal of Organic Chemistry2000Vol. 65(16), pp. 4791–4795
Citations Over Time
Abstract
Preparation of dibenzyl sulfoxylate 7a and 4-substituted benzyl sulfoxylates (7b, 4-NO(2); 7c, 4-Cl; 7d, 4-CH(3)O, 7e: 4-CH(3)) are reported. The unexpected stability of 7b has permitted the first X-ray determination at room temperature of a sulfoxylate. The thermal isomerization of sulfoxylates 7b-c to sulfinates 8b-c was studied in different solvents (toluene-d(8), CDCl(3), and CD(3)CN) and interpreted as a concerted unimolecular process following first-order kinetics.
Related Papers
- → Isomerization reactions of n-hexane on partially reduced MoO3/TiO2(2007)33 cited
- → Anisatinic acid and isoanisatinic acid, isomerization products of anisatin(1968)10 cited
- → Isomerization of 1,3‐Diarylprop‐2‐yn‐1‐ols to Chalcones in the Presence of Potassium Hydroxide.(2005)1 cited
- → Novel insight into the photochemical cis-trans isomerization of olefins.(1986)10 cited
- → Isomerization(2017)