Picosecond Hydrogen Transfer in the Phenol-(NH3)n=1-3 Excited State
The Journal of Physical Chemistry A2000Vol. 104(40), pp. 9087–9090
Citations Over TimeTop 10% of 2000 papers
Abstract
The phenol−(NH3)n=1,2,3 (S1) lifetimes have been measured near their band origins by a picosecond pump/probe scheme. The very short lifetimes observed reveal that the excited clusters undergo a reactive process, namely the following dissociative hydrogen transfer reaction: PhOH*−(NH3)n → PhO• + NH4(NH3)n-1.
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