Ab Initio Investigation of the Temporary Anion States of Perfluoroethane
The Journal of Physical Chemistry A2000Vol. 104(42), pp. 9605–9612
Citations Over TimeTop 20% of 2000 papers
Abstract
The stabilization method is used to characterize the temporary anion states of C2F6. Based on the theoretical results, we assign the lowest-energy feature in the electron transmission spectrum of C2F6 to the 2Eu ground-state anion and the second feature to overlapping 12Au, 12A1g, 22Au, and 12Eg anion states. It is also proposed that the bimodal kinetic energy distribution of the F- ions produced in the dissociative attachment of near 5 eV electrons on C2F6 is due to the Jahn−Teller effect.
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