Marcus Theory for Outer-Sphere Heterogeneous Electron Transfer: Predicting Electron-Transfer Rates for Quinones
The Journal of Physical Chemistry B2004Vol. 108(34), pp. 13047–13051
Citations Over TimeTop 23% of 2004 papers
Abstract
Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k0 on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and the predictions are compared to experimental measurements.
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