Observation of the Ã−X Electronic Transition of the 1-C3H7O2 and 2-C3H7O2 Radicals Using Cavity Ringdown Spectroscopy
The Journal of Physical Chemistry A2005Vol. 109(7), pp. 1308–1315
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Sergey J. Zalyubovsky, Brent G. Glover, Terry A. Miller, Carrigan J. Hayes, John K. Merle, Christopher M. Hadad
Abstract
Cavity ringdown spectra of the A-X electronic transition of the 1-propyl and 2-propyl peroxy radicals are reported. Spectroscopic assignments are facilitated by implementing several production mechanisms, either isomer-specific or not. Assignments of specific spectral lines to particular conformers of a given isomer are suggested. Observations on the temporal decay of the various species are reported.
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