In Situ Ultraviolet Raman Spectroscopy of the Reduction of Chromia on Alumina Catalysts
The Journal of Physical Chemistry B2004Vol. 109(1), pp. 352–356
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Abstract
A fluidized bed in situ cell is used to examine the chromia on alumina catalyst surface. The loading is varied from 1 to 20% chromium oxide on alumina. The structure of the surface is monitored as a function of temperature, reduction, and hydration. This is the first study to use ultraviolet excitation to study a reduced chromium catalyst surface. Reduction of the sample in hydrogen gas leads to the formation of noncrystalline Cr(3+) species. Addition of potassium to the surface reduces the size of the chromia clusters.
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