Experimental and Modeling Study of Methyl Cyclohexane Pyrolysis and Oxidation
The Journal of Physical Chemistry A2005Vol. 110(1), pp. 114–131
Citations Over TimeTop 10% of 2005 papers
Abstract
Although the combustion chemistry of aliphatic hydrocarbons has been extensively documented, the oxidation of cyclic hydrocarbons has been studied to a much lesser extent. To provide a deeper understanding of the combustion chemistry of naphthenes, the oxidation of methylcyclohexane was studied in a series of high-temperature shock tube experiments. Ignition delay times for a series of mixtures, of varying methylcyclohexane/oxygen equivalence ratios (phi=0.5, 1.0, 2.0), were measured over reflected shock temperatures of 1200-2100 K and reflected shock pressures of 1.0, 2.0, and 4.0 atm. A detailed chemical kinetic mechanism has been assembled to simulate the shock tube results and flow reactor experiments, with good agreement observed.
Related Papers
- → Excess Volumes of Mixtures of Cycloalkanes and Methylcycloalkanes(1980)83 cited
- → Vapor-Liquid Equilibria and Liquid Density Behaviors for Hexane-Cyclohexane, Cyclohexane-Methylcyclohexane and Cyclohexane-Toluene Systems.(1992)11 cited
- → Volumetric properties of ternary pseudo-binary mixtures at the temperature 298.15 K. I. {(Benzene+cyclohexane, or methylcyclohexane)+(acrylonitrile+cyclohexane, or methylcyclohexane)}(1998)6 cited
- → Effects of the Presence of Cyclohexane or Methylcyclohexane on the Densities and Volumetric Properties of the Mixture (Benzene + Propionitrile)(2005)4 cited
- → Volumetric Properties of Ternary-Pseudobinary Mixtures Containing Benzene and Cyclohexane(2005)3 cited