Photochemical Synthesis of the Cyanodiacetylene HC5N: A Cryogenic Matrix Experiment
The Journal of Physical Chemistry A2006Vol. 110(7), pp. 2371–2377
Citations Over TimeTop 11% of 2006 papers
Abstract
The reactivity of intermolecular complexes cyanoacetylene:acetylene and dicyanoacetylene:acetylene, trapped in solid argon matrixes at 10 K and irradiated with vacuum UV, has been studied. FTIR measurements, together with 2H, 15N, 13C labeling experiments and with density functional theory (DFT) calculations (B3LYP/aug-cc-pVTZ), pointed to the formation of cyanodiacetylene HC5N (cyanobutadiyne). This synthetic route is potentially important for chemical models of the Titan's atmosphere.
Related Papers
- → Condensed species in Titan's stratosphere: Confirmation of crystalline cyanoacetylene (HC3N) and evidence for crystalline acetylene (C2H2) on Titan(2005)50 cited
- → Semi-conducting cyclic copolymers of acetylene and propyne(2021)20 cited
- → Primary Reactions in the Mercury-Photosensitized Decomposition of 1-Butyne, Propyne, and Acetylene at Low Pressures(1963)26 cited
- → The competitive oxidation of acetylene and propyne(1967)3 cited
- → Corrigendum to “Condensed species in Titan's stratosphere: Confirmation of crystalline cyanoacetylene (HC3N) and evidence for crystalline acetylene (C2H2) on Titan” [Icarus 178 (2005) 165–170](2006)