Linearly Polarized Emission of an Organic Semiconductor Nanobelt
The Journal of Physical Chemistry B2006Vol. 110(25), pp. 12327–12332
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Aniket Datar, Kaushik Balakrishnan, Xiaomei Yang, Xiaobing Zuo, Jialing Huang, Randy Oitker, Max Yen, Jincai Zhao, David M. Tiede, Ling Zang
Abstract
Linearly polarized emission has been observed for the nanobelts fabricated from a perylene diimide molecule through both solution-based and surface-supported self-assembling. The measurement of polarized emission was performed over single nanobelts with use of a near-field scanning optical microscope (NSOM) adapted with emission polarization (by putting a planar polarizer before the detector). Rotating the emission polarizer (from 0 degrees to 180 degrees) changed the emission intensity in a way depending on the relative angle between the long axis of the belt and the polarizer with a minimum of intensity detected at ca. 78 degrees, which is indicative of the tilted stacking of molecules along the belt direction.
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