Photolysis of Polycyclic Aromatic Hydrocarbons on Water and Ice Surfaces
Citations Over TimeTop 10% of 2007 papers
Abstract
Laser-induced fluorescence detection was used to measure photolysis rates of anthracene and naphthalene at the air-ice interface, and the kinetics were compared to those observed in water solution and at the air-water interface. Direct photolysis proceeds much more quickly at the air-ice interface than at the air-water interface, whereas indirect photolysis due to the presence of nitrate or hydrogen peroxide appears to be suppressed at the ice surface with respect to the liquid water surface. Both naphthalene and anthracene self-associate readily on the ice surface, but not on the water surface. The increase in photolysis rates observed on ice surfaces is not due to this self-association, however. The wavelength dependence of the photolysis indicates that it is due to absorption by the PAH. No dependence of the rate on temperature is seen, either at the liquid water surface or at the ice surface. Molecular oxygen appears to play a complex role in the photolytic loss mechanism, increasing or decreasing the photolysis rate depending on its concentration.
Related Papers
- → Polymorphism in Benzene, Naphthalene, and Anthracene at High Pressure(1970)101 cited
- → Hydrogenation of naphthalene and anthracene on Pt/C catalysts(2018)17 cited
- → Temperature Dependence of the Entropy and the Heat Capacity Calculated from the Raman Frequency Shifts for Solid Benzene, Naphthalene and Anthracene(2022)2 cited
- Comparison of Analytical Methods for Three Carcinogenic Polycyclic Aromatic Hydrocarbons(PAHs):naphthalene,anthracene,pyrene(2009)
- Inner-assembly singlet energy transfer in naphthalene-anthracene system linked by 2-ureido-4{1H}-pyrimidinone binding module(2004)