UV and IR Absorption Cross-sections of HCHO, HCDO, and DCDO
The Journal of Physical Chemistry A2007Vol. 111(45), pp. 11506–11513
Citations Over TimeTop 13% of 2007 papers
Aline Gratien, Elna J. K. Nilsson, Jean‐François Doussin, Matthew S. Johnson, Claus J. Nielsen, Yngve Stenstrøm, Bénédicte Picquet‐Varrault
Abstract
UV (240-370 nm) and IR (3200-1500 cm(-1)) absorption cross-sections of HCHO, HCDO, and DCDO in a bath gas of N(2) at atmospheric pressure and 296 K are reported from simultaneous measurements in the two spectral regions. Cross-sections were placed on an absolute scale through quantitative conversion of formaldehyde to CO and HCOOH by titration with Br atoms, also monitored by FTIR. The integrated UV absorption cross-sections of HCHO, HCDO, and DCDO are equal to within the experimental uncertainty.
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