How Does Thermal Poling Affect the Structure of Soda-Lime Glass?
The Journal of Physical Chemistry C2010Vol. 114(29), pp. 12754–12759
Citations Over TimeTop 10% of 2010 papers
Marc Dussauze, Vincent Rodriguez, A. A. Lipovskiĭ, Mihail Petrov, Charmayne Smith, K. Richardson, Thierry Cardinal, Eveline Fargin, E. I. Kamitsos
Abstract
Soda lime glasses polarized either with an open or a blocking anode have been characterized by IR reflectance spectroscopy and a combined analysis of second harmonic generation and Raman imaging. The experimental results clearly show that the electrode nature influences strongly (i) the thickness of the space charge layer, (ii) the χ(2) efficiency, and (iii) the structural rearrangements. Besides, using theoretical models accounting for charge carriers’ mobilities, the respective influence of two distinct compensation mechanisms, that is an injection of positive charges (H3O+/H+ ions) or a drift of oxygen ions, have been confirmed.
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