Isolation and Characterization of Carbene Derivatives of La@C82(Cs)
The Journal of Physical Chemistry A2008Vol. 112(6), pp. 1294–1297
Citations Over TimeTop 10% of 2008 papers
Takeshi Akasaka, Takayoshi Kono, Yoichiro Matsunaga, Takatsugu Wakahara, Tsukasa Nakahodo, Midori O. Ishitsuka, Yutaka Maeda, Takahiro Tsuchiya, Tatsuhisa Kato, Michael T. H. Liu, Naomi Mizorogi, Zdeněk Slanina, Shigeru Nagase
Abstract
The photochemical reaction of La@C82(Cs) with 2-adamantane-2,3-[3H]-diazirine (1) affords the adduct 2 of La@C82(Cs) with adamantylidene (Ad:) in a high selectivity. The two isomers of La@C82(Cs)(Ad), 2a and 2b, are isolated by HPLC and characterized by electron spin resonance, mass, and UV-vis-near-infrared spectroscopies. The electronic properties of 2a and 2b are very similar to that of the pristine La@C82(Cs), suggesting that 2a and 2b retain the essential electronic and structural character of La@C82(Cs).
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