Interactions of Cl− and OH Radical in Aqueous Solution
The Journal of Physical Chemistry A2009Vol. 113(31), pp. 8823–8825
Citations Over TimeTop 23% of 2009 papers
Abstract
There is a considerable controversy surrounding the nature of the Cl-/OH complex in aqueous solution, which appears as a byproduct of the irradiation of salt solutions in nuclear reactor operation, radioactive waste storage, medicine, and environmental problems. In this work, we report results of combined quantum mechanical molecular mechanics calculations of ground-state free-energy surfaces and absorption spectrum through the CCSDT level of theory that are consistent with the experimental data and suggest that hemibonded HOCl- species may indeed exist in bulk aqueous solution.
Related Papers
- → Effect of heat treatment and salt addition on the physicochemical properties and quality of fresh noodles(2020)23 cited
- → THE EFFECT of SELECTED SALTS ON the MICROWAVE HEATING of STARCH SOLUTIONS(2000)15 cited
- → Conductivity properties of hyaluronate salts in simple salt-free and sample salt-containing solutions(1984)3 cited
- → Salt seeking by means of food and fluid selection in adrenalectomized rats(1979)9 cited
- Study on extraction technique of salt-soluble protein of proso millet(2006)