Spatial Control of 3D Energy Transfer in Supramolecular Nanostructured Host−Guest Architectures
The Journal of Physical Chemistry B2009Vol. 113(31), pp. 10566–10570
Citations Over TimeTop 19% of 2009 papers
Lucas Viani, Lars Poulsen Tolbod, Mikaël Jazdzyk, Greta Pătrinoiu, Fabrizio Cordella, Andrea Mura, Giovanni Bongiovanni, Chiara Botta, David Beljonne, Jérôme Cornil, Michael Hanack, Hans‐Joachim Egelhaaf, Johannes Gierschner
Abstract
Systematic control of 3D energy transfer (ET) dynamics is achieved in supramolecular nanostructured host-guest systems using spacer-functionalized guest chromophores. Quantum chemistry-based Monte Carlo simulations reveal the strong impact of the spacer length on the ET dynamics, efficiency, and dimensionality. Remarkably high exciton diffusion lengths demonstrate that there is ample scope for optimizing oligomeric or polymeric optoelectronic devices.
Related Papers
- → Synthesis of Chromophores with Extremely High Electro-optic Activity. 1. Thiophene-Bridge-Based Chromophores(2002)116 cited
- → Using phenoxazine and phenothiazine as electron donors for second-order nonlinear optical chromophore: Enhanced electro-optic activity(2014)55 cited
- → The design of nonlinear optical chromophores exhibiting large electro-optic activity and high thermal stability: The role of donor groups(2016)33 cited
- → Single Oligomer Spectra Probe Chromophore Nanoenvironments of Tetrameric Fluorescent Proteins(2006)20 cited
- → Factors affecting the estimation of the relative amount of chromophore and chromophore area by the two-wavelength method of patau and ornstein(1976)7 cited