Extended Irreversible Thermodynamics of Chemically Reacting Systems
The Journal of Physical Chemistry B1999Vol. 103(5), pp. 861–867
Citations Over TimeTop 13% of 1999 papers
Abstract
A phenomenological model for the thermodynamics of nonequilibrium chemically reacting systems is proposed. It is based on the assumption that the specific entropy of the system is a function of the net reaction rate, as well as of the classical variables. This assumption is confirmed by the kinetic theory of reacting dilute gas mixtures.
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