Molecular Beam Studies of HCl Interactions with Pure and HCl-Covered Ice Surfaces

Abstract

The dynamics of HCl collisions with ice surfaces is studied using molecular beam techniques. The experiments are carried out with a water vapor pressure of up to 3 × 10-5 mbar outside the ice surface, which allows experiments to be performed at surface temperatures of 127−180 K. At the higher surface temperatures, the ice has a very dynamic character and constantly undergoes evaporation and condensation. Angular-resolved intensity and time-of-flight distributions are measured with mass spectrometry, and the effects of surface temperature, incident kinetic energy, and HCl surface coverage are investigated. The dominating outcome of the surface interaction is loss of HCl by sticking to the surface with a residence time of more than 1 ms. Small direct scattering and trapping-desorption channels are also observed depending on the conditions. For a pure ice surface the sticking probability is 1.00 ± 0.02 at thermal incident kinetic energies, E, while a small direct scattering channel is observed when E is increased, reaching a probability of 0.015 ± 0.005 at E = 0.53 eV. For HCl-covered ice surfaces at 165 K and with thermal incident energies, the sticking probability is 0.88 ± 0.03 and a trapping-desorption channel (surface residence time less than 30 μs) with a probability of 0.12 ± 0.02 is also observed. A direct scattering channel opens at higher energies, reaching a probability of 0.08 ± 0.02 at E = 0.53 eV. For all surface conditions, the collisions are highly inelastic with large energy loss observed for the directly scattered flux, comparable to the results for the previously studied Ar−ice system.

Molecular Beam Studies of HCl Interactions with Pure and HCl-Covered Ice Surfaces

Citations Over TimeTop 10% of 2000 papers

Abstract

Related Papers