Highly Active, Nonprecious Metal Perovskite Electrocatalysts for Bifunctional Metal–Air Battery Electrodes
Citations Over TimeTop 10% of 2013 papers
Abstract
Perovskites are of great interest as replacements for precious metals and oxides used in bifunctional air electrodes involving the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR). Herein, we report the synthesis and activity of a phase-pure nanocrystal perovskite catalyst that is highly active for the OER and ORR. The OER mass activity of LaNiO3, synthesized by the calcination of a rapidly dried nanoparticle dispersion and supported on nitrogen-doped carbon, is demonstrated to be nearly 3-fold that of 6 nm IrO2 and exhibits no hysteresis during oxygen evolution. Moreover, strong OER/ORR bifunctionality is shown by the low total overpotential (1.02 V) between the reactions, on par or better than that of noble metal catalysts such as Pt (1.16 V) and Ir (0.92 V). These results are examined in the context of surface hydroxylation, and a new OER cycle is proposed that unifies theory and the unique surface properties of LaNiO3.
Related Papers
- → Facile synthesis of interlaced flower-like layered double hydroxides grown on porous CoMoP as a highly efficient electrocatalyst for hydrogen evolution reaction(2023)33 cited
- → Oxygen Evolution Reaction (OER) on Clean and Oxygen Deficient Low-Index SrTiO3 Surfaces: A Theoretical Systematic Study(2019)20 cited
- → Cover Picture: A 3D Nanoporous Ni–Mo Electrocatalyst with Negligible Overpotential for Alkaline Hydrogen Evolution (ChemElectroChem 7/2014)(2014)4 cited
- → A 3D Nanoporous Ni–Mo Electrocatalyst with Negligible Overpotential for Alkaline Hydrogen Evolution(2014)4 cited
- Preparation and characterization of La_(0.6) Ca_(0.4) CoO_3 as bifunctional oxygen electrode electrocatalyst(2004)