Creation of Novel Double-Helical Silica Nanotubes Using Binary Gel System
Langmuir2002Vol. 18(23), pp. 8724–8727
Citations Over TimeTop 10% of 2002 papers
Abstract
Sugar-based gelator p-dodecanoyl-aminophenyl-β-d-glucopyranoside 1 has been shown to self-assemble in the presence of p-aminophenyl glucopyranoside 2 into double-helical fibers with diameters of 3−25 nm and lengths of several micrometers. The sol−gel polymerization of tetraethoxysilane (TEOS) was carried out using a binary gel system. The double-helical structure of the organic assemblies could be accurately transcribed into the silica structure. This result indicates that the amino group of the p-aminophenyl glucopyranoside acts as the efficient driving force to create novel double-helical silica nanotubes.
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