High Uptakes of CO2 and CH4 in Mesoporous Metal—Organic Frameworks MIL-100 and MIL-101
Langmuir2008Vol. 24(14), pp. 7245–7250
Citations Over TimeTop 1% of 2008 papers
Philip L. Llewellyn, Sandrine Bourrelly, Christian Serre, Alexandré Vimont, Marco Daturi, Lomig Hamon, Guy De Weireld, Jong‐San Chang, Do‐Young Hong, Young Kyu Hwang, Sung Hwa Jhung, Gérard Férey
Abstract
Mesoporous MOFs MIL-100 and MIL-101 adsorb huge amounts of CO2 and CH4. Characterization was performed using both manometry and gravimetry in different laboratories for isotherms coupled with microcalorimetry and FTIR to specify the gas-solid interactions. In particular, the uptake of carbon dioxide in MIL-101 has been shown to occur with a record capacity of 40 mmol g(-1) or 390 cm3STP cm(-3) at 5 MPa and 303 K.
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