Understanding Organic Film Behavior on Alloy and Metal Oxides
Citations Over TimeTop 10% of 2009 papers
Abstract
Native oxide surfaces of stainless steel 316L and Nitinol alloys and their constituent metal oxides, namely nickel, chromium, molybdenum, manganese, iron, and titanium, were modified with long chain organic acids to better understand organic film formation. The adhesion and stability of films of octadecylphosphonic acid, octadecylhydroxamic acid, octadecylcarboxylic acid, and octadecylsulfonic acid on these substrates were examined in this study. The films formed on these surfaces were analyzed by diffuse reflectance infrared Fourier transform spectroscopy, contact angle goniometry, atomic force microscopy, and matrix-assisted laser desorption ionization mass spectrometry. The effect of the acidity of the organic moiety and substrate composition on the film characteristics and stability is discussed. Interestingly, on the alloy surfaces, the presence of less reactive metal sites does not inhibit film formation.
Related Papers
- → Heptacoordinated Molybdenum(VI) Complexes of Phenylenediamine Bis(phenolate): A Stable Molybdenum Amidophenoxide Radical(2013)31 cited
- → ChemInform Abstract: USE OF η6‐ARYLPHOSPHINE COMPLEXES OF MOLYBDENUM(0) FOR THE SYNTHESIS OF COMPLEXES CONTAINING MOLYBDENUM‐MOLYBDENUM AND MOLYBDENUM‐TUNGSTEN QUADRUPLE BONDS(1985)
- → ChemInform Abstract: MOLYBDENUM(VI)‐DIOXO, MOLYBDENUM(V)‐OXO, AND MOLYBDENUM(IV)‐OXO COMPLEXES WITH 2,3:8,9‐DIBENZO‐1,4,7,10‐TETRATHIADECANE. MODELS FOR THE MOLYBDENUM BINDING SITE OF THE MOLYBDENUM COFACTOR(1985)
- → ChemInform Abstract: VERSATILITY OF TETRAKIS(TERT‐BUTYLTHIOLATO)MOLYBDENUM. SELECTIVE FORMATION OF A SERIES OF THIOLATO‐MOLYBDENUM(I), ‐MOLYBDENUM(II), AND ‐MOLYBDENUM(IV) COMPOUNDS(1981)
- → Low-temperature Thermal Capacity Of Some Molybdenum-chalcogenides, Molybdenum-chlorides, And Molybdenum-oxychlorides.(1974)