Dendrimers Based on Thermally Reversible Furan−Maleimide Diels−Alder Adducts
Macromolecules2007Vol. 40(4), pp. 818–823
Citations Over TimeTop 10% of 2007 papers
Abstract
Thermally labile dendrimers based on the reversible furan−maleimide Diels−Alder reaction are described. First through fourth generation benzyl aryl ether based dendrons 3a−d that contained furan moieties at their focal point were allowed to react with bismaleimide central linker 4 to provide the corresponding dendrimers 5−8. Thermal degradation and reassembly of these dendrimers were studied under a variety of conditions and monitored by GPC and NMR.
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