Pushing the Limits for Thiol−Ene and CuAAC Reactions: Synthesis of a 6th Generation Dendrimer in a Single Day
Macromolecules2010Vol. 43(16), pp. 6625–6631
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Per Antoni, Maxwell J. Robb, Luis M. Campos, María I. Montañez, Anders Hult, Eva Malmström, Michael Malkoch, Craig J. Hawker
Abstract
Dendrimer synthesis should not be tedious and time-consuming. By utilizing an AB2−CD2 approach and having orthogonal, “clickable” groups on each monomer, the time for dendrimer assembly can be drastically reduced. This was shown by preparation of a sixth generation dendrimer from starting monomer units in a single day.
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