Efficient Amine End-Functionalization of Living Ring-Opening Metathesis Polymers
Macromolecules2012Vol. 45(11), pp. 4447–4453
Citations Over TimeTop 10% of 2012 papers
Abstract
An efficient strategy for the synthesis of monoamine end-functionalized living polymers using ring-opening metathesis polymerization with ruthenium initiators is reported. A new end-capping agent for this purpose was synthesized, and its efficiency for end-functionalization was evaluated using two common ruthenium-based initiators. Finally, terminal cross-metathesis was also explored as another alternative toward the synthesis of amine end-functionalized polymers, and the comparison between the two techniques is presented.
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