Preparation and Mechanical Properties of Polypropylene−Clay Hybrids
Citations Over TimeTop 1% of 1997 papers
Abstract
Polypropylene (PP)−clay hybrids (PPCH) have been prepared by simple melt-mixing of three components, i.e., PP, maleic anhydride modified polypropylene oligomers (PP-MA), and clays intercalated with stearylammonium. The dispersibility of 10-Å-thick silicate layers of the clays in the hybrids was investigated by using a transmission electron microscope and X-ray diffractometer. It is found that there are two important factors to achieve the exfoliated and homogeneous dispersion of the layers in the hybrids: (1) the intercalation capability of the oligomers in the layers and (2) the miscibility of the oligomers with PP. Almost complete hybrids were obtained in the case where the PP-MA has both intercalation capability and miscibility. The hybrids exhibit higher storage moduli compared to those of PP especially in the temperature range from Tg to 90 °C. The highest relative storage modulus at 80 °C of the hybrid based on a mica and the miscible PP-MA is as high as 2.0 to that of PP and is 2.4 to that of the PP/PP-MA mixture, which is considered to be the matrix of the PPCH. Also, the effects of the kinds of clays and oligomers on the dynamic moduli are discussed.
Related Papers
- → Intercalation of both CTMAB and Al13 into montmorillonite(2009)49 cited
- → The intercalation of 2,2′-bipyridine and 1,10-phenanthroline and their complexes with iron within the interlayer regions of montmorillonite clay(1990)17 cited
- Study on Modification of Polypropylene and Polypropylene Packaging Film(2006)
- Study on the preparation of PP/MMT nanocomposites(2002)
- Progress of Polypropylene/Montmorillonite Composites(2011)