Low-Temperature Preparations of Unimolecular Nitroxide Initiators for “Living” Free Radical Polymerizations
Macromolecules1997Vol. 30(21), pp. 6445–6450
Citations Over TimeTop 10% of 1997 papers
Abstract
Low-temperature methods for the preparation of monomeric initiators for use in “living” free radical olefin polymerizations have been developed. Oxidative methods for generating carbon radicals in the presence of nitroxide traps such as TEMPO utilize PbO2 with benzylic, alkyl, or phenylhydrazines or CuCl2 with lithium enolates. Photolytic methods employ [Cp(CO)2Fe]2 with a benzylic bromide, diphenyl disulfide with styrene, or di-tert-butyl peroxide with ethers. The use of di-tert-butyl hyponitrite with ethers generates carbon radicals at 50 °C that are trapped by TEMPO.
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