Triptycene-Based Microporous Polymers: Synthesis and Their Gas Storage Properties
ACS Macro Letters2011Vol. 1(1), pp. 190–193
Citations Over TimeTop 10% of 2011 papers
Abstract
A novel kind of star triptycene-based microporous polymer (STPs) was synthesized efficiently from trihalotriptycenes by nickel(0)-catalyzed Ullmann cross-coupling reactions. STPs display a BET surface area of 1305 m2 g-1 and 1990 m2 g-1, and reversibly adsorb 1.60 and 1.93 wt % H2 at 1.0 bar/77 K, 16.15 and 18.20 wt % CO2 at 1.0 bar/273 K for STP-I and STP-II, respectively.
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