Observation of a Burstein–Moss Shift in Rhenium-Doped MoS2 Nanoparticles
ACS Nano2013Vol. 7(4), pp. 3506–3511
Citations Over TimeTop 10% of 2013 papers
Abstract
We investigated the optical properties of rhenium-doped MoS2 nanoparticles and compared our findings with the pristine and bulk analogues. Our measurements reveal that confinement softens the exciton positions and reduces spin-orbit coupling, whereas doping has the opposite effect. We model the carrier-induced exciton blue shift in terms of the Burstein-Moss effect. These findings are important for understanding doping and finite length scale effects in low-dimensional nanoscale materials.
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