Structure Revision and Assignment of Absolute Stereochemistry of a Marine C21 Bisfuranoterpene
Journal of Natural Products2001Vol. 64(5), pp. 638–639
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Abstract
The C21 bisfuranoterpene (-)-isotetradehydrofurospongin-1 (6), previously isolated from a Western Australian Spongia sp., has been reisolated from a specimen of Spirastrella papilosa collected during scientific trawling operations in the Great Australian Bight. A 2D NMR analysis of 6 has prompted reassignment of the published structure 5, while degradation and chiral HPLC analysis have allowed determination of the absolute stereochemistry.
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