Sulfated Triterpene Derivatives from Fagonia arabica
Journal of Natural Products2007Vol. 70(4), pp. 584–588
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Angela Perrone, Milena Masullo, Carla Bassarello, Arafa I. Hamed, Maria Antonietta Belisario, Cosimo Pìzza, Sonia Piacente
Abstract
Two new sulfated triterpenes (1, 6) and four new sulfated triterpene glycosides (2-5) have been isolated from the aerial parts of Fagonia arabica. Their structures were established by spectroscopic data analysis. Compounds 1/2 and 3/4 are sulfated derivatives of the rare sapogenins 3beta,27-dihydroxyolean-12-en-28-oic acid and 3beta,27-dihydroxyurs-12-en-28-oic acid, respectively. Compound 5 is an unusual disulfated oleanene derivative characterized by the occurrence of a 13,18-double bond, while compound 6 is the first reported naturally occurring saturated and sulfated pentacyclic triterpene of the taraxastane series with a C-20,28 lactone unit.
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