Enantioselective Synthesis of the Tetrahydrofuran Lignans (–)- and (+)-Magnolone

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Abstract

The optically pure trisubstituted 7'-oxotetrahydrofuran lignans (-)- and (+)-magnolone ( 1) were synthesized by employing stereoselective S N1 intramolecular cyclization as a key reaction. The absolute configuration of naturally occurring (-)-magnolone was determined as (7 S,8 R,8' S).

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