Silylcupration of Allenes and Subsequent Electrophilic Trapping by Allylic Phosphates. A Novel Approach to Silylated 1,4-Diene Systems
Organic Letters2000Vol. 2(9), pp. 1237–1239
Citations Over TimeTop 14% of 2000 papers
Abstract
[formula: see text] Silylcupration of allenes with a lower order silylcuprate reagent followed by an electrophilic trapping reaction with allylic diphenyl phosphates has been studied. This reaction provides a new route to 1,4-diene systems having an allylsilane moiety.
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